list
my_users:
  - aaa
  - bbb
  - ccc
dict
my_users:
  - Name: aaa
  - Name: bbb
  - Name: ccc
playbook
- name: Transform data
  vars:
    orig_users:
      - aaa
      - bbb
      - ccc
    my_users: []
  set_fact:
    my_users: "{{ my_users + [{} | combine({'Name': item})] }}"
  loop: "{{ orig_users }}"

Explanation:

  1. Use the combine filter to build a dict
  2. Use loop to iterate orig_users
  3. Use my_users + [{} | combine({‘Name’: item})] to append to the list```